Efficient single-atom Ni for catalytic transfer hydrogenation of furfural to furfuryl alcohol
نویسندگان
چکیده
A single-atom Ni catalyst is utilized for the first time in catalytic transfer hydrogenation of furfural to furfuryl alcohol.
منابع مشابه
Hydrogenation and hydrogenolysis of furfural and furfuryl alcohol catalyzed by ruthenium(II) bis(diimine) complexes
The catalytic activity of ruthenium(II) bis(diimine) complexes cis-[Ru(6,6′-Cl2bpy)2(OH2)2](Z)2 (1, Z=CF3SO3; 2, Z= (3,5-(CF3)2C6H3)4B, i.e. BArF) and cis-[Ru(4,4′-Cl2bpy)2(OH2)2](Z)2 (3, Z=CF3SO3; 4, Z=BArF) for the hydrogenation and/or the hydrogenolysis of furfural (FFR) and furfuryl alcohol (FFA) was investigated. Themolecular structures of cis-[Ru(4,4′-Cl2bpy)2(CH3CN)2](CF3SO3)2 (3′) and d...
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Graphitic carbon nitride nanosheets were investigated for developing effective Pt catalyst supports for selective hydrogenation of furfural to furfuryl alcohol in water. The nanosheets with an average thickness of about 3 nm were synthesized by a simple and green method through thermal oxidation etching of bulk g-C3N4 in air. Combined with the unique feature of nitrogen richness and locally con...
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Green, inexpensive, and robust copper-based heterogeneous catalysts achieve 100 % conversion and 99 % selectivity in the conversion of furfural to furfuryl alcohol when using cyclopentyl-methyl ether as green solvent and microwave reactors at low H2 pressures and mild temperatures. The utilization of pressurized microwave reactors produces a 3-4 fold increase in conversion and an unexpected enh...
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Furfural is one of the most promising chemical platforms with bright perspective with respect to the production of biobased chemicals and fuels from lignocellulosic material. Globally, the majority of this biomass derived chemical is converted into furfuryl alcohol, a building block in polymers industry. The vapor-phase hydrogenation of furfural over copper species dispersed on two types of sil...
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Co-precipitated Cu-MgO catalysts were prepared and evaluated for the gas-phase hydrogenation of furfural. The effect of heating rate at the calcination step was studied by comparing the performance of three catalysts prepared via the same procedure but calcined at different heating rates. The results established that altering the heating rate could influence the structural properties of the cat...
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ژورنال
عنوان ژورنال: Journal of materials chemistry. A, Materials for energy and sustainability
سال: 2021
ISSN: ['2050-7488', '2050-7496']
DOI: https://doi.org/10.1039/d0ta10838c